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Introduction
1. CARS
2. Psych/soc
3. Bio/biochem
4. Chem/phys
4.1 4A: Translational motion, forces, work, energy, and equilibrium
4.2 4B: Fluids in circulation of blood, gas movement, and gas exchange
4.3 4C: Electrochemistry and electrical circuits and their elements
4.4 4D: How light and sound interact with matter
4.4.1 Geometrical optics
4.4.2 Molecular structure and absorption spectra
4.4.3 Sound
4.4.4 Light, electromagnetic radiation
4.5 4E: Atoms, nuclear decay, electronic structure, and atomic chemical behavior
4.6 5A: Unique nature of water and its solutions
4.7 5B: Nature of molecules and intermolecular interaction
4.8 5C: Separation and purification methods
4.9 5D: Structure, function, and reactivity of bio-relevant molecules
4.10 5E: Principles of chemical thermodynamics and kinetics, enzymes
Wrapping up
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4.4.4 Light, electromagnetic radiation
Achievable MCAT
4. Chem/phys
4.4. 4D: How light and sound interact with matter
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Light, electromagnetic radiation

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Interference; Young’s double-slit experiment

Light is a form of electromagnetic radiation that behaves as a wave, exhibiting phenomena such as interference. A classic example is the Young’s double-slit experiment, where light passes through two parallel slits. For interference to occur, the light from both slits must be coherent, meaning it maintains a constant phase relationship, and monochromatic, having only one wavelength.

The resulting pattern is described by the equation

dsinθ=mλ

where d is the distance between the slits, θ is the angle of the fringe relative to the center, m is the order of the fringe, and λ is the wavelength.

  • Bright fringes appear at m=0,±1,±2, etc.
  • Dark fringes occur at m=±0.5,±1.5,±2.5, etc.

Thin films, diffraction grating, single-slit diffraction

Diffraction is another wave-like behavior of light when it interacts with various obstacles and media. In thin films, light reflects off both the outer and inner surfaces, causing the reflected waves to interfere with each other; this interference produces colorful patterns, as seen in an oil film on water.

A diffraction grating is a device featuring many closely spaced slits that cause light to spread out and interfere in a pattern similar to that of the double-slit experiment. The positions of the interference fringes are given by the equation dsinθ=mλ, where d is the distance between the slits, θ is the angle relative to the normal, λ is the wavelength, and m represents the order of the fringe.

Other diffraction phenomena, X-ray diffraction

When light encounters a small opening or obstacle, it does not simply form a clear image of that object; instead, it produces a pattern of interference due to diffraction. For instance, when light shines through a pinhole, a series of concentric bright and dark circles appears on the screen, with a prominent bright spot at the center.

Similarly, when light passes the edge of an opaque boundary, it does not create a sharply defined shadow; instead, fringes of alternating brightness form along the edge. In another example, light passing by a small object like a penny creates a shadow that is not completely dark, but rather shows a bright central spot surrounded by rings of light and dark, demonstrating the wave nature of light.

In X-ray diffraction, high-energy X-rays are directed at a crystal, where they diffract off the regularly spaced atoms. The resulting interference pattern, which consists of a series of spots or rings, provides detailed information about the molecular structure of the crystal.

Polarization of light: linear and circular

Polarization of light describes the orientation of its electric field oscillations. In unpolarized light, the electric field vibrates in multiple directions, whereas in polarized light, it is confined to a single plane.

This characteristic can be observed and utilized in several ways:

  • Selective absorption employs a polarizer to block all but the light waves that vibrate in one desired direction.
  • Reflection at specific angles causes light to become polarized, as the reflected waves align in a single plane.
  • Double refraction occurs in birefringent materials, which split an incoming light beam into two rays with perpendicular polarizations.
  • Scattering by air molecules results in partially polarized light, and optically active substances can rotate the plane of polarization either clockwise or counterclockwise.

The Doppler effect describes how the frequency of light changes when there is relative motion between the light source and the observer. When the source and observer move apart, the observed frequency decreases, resulting in a red shift, which is why astronomical objects moving away from us often appear redder than they are. Conversely, when they move toward each other, the observed frequency increases, producing a blue shift, causing the light to appear bluer. The equations used for these shifts are analogous to those for sound waves, except that the speed of light replaces the speed of sound.

The Doppler effect equation

fo​=fs​(v±vs​v±vo​​)

…where:

  • fo​​ is the frequency experienced by the observer
  • fs​​ is the frequency emitted by the source
  • v is the speed of the wave (most frequently the speed of sound or light)
  • vo​ is the velocity of the observer (00 if it is at rest)
  • vs​ is the velocity of the source (00 if it is at rest)

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Classification of electromagnetic spectrum, photon energy E=hf

The photon model of light treats electromagnetic radiation as packets of energy called photons, each possessing energy proportional to its frequency. This relationship is given by E=hf, where h is Planck’s constant and f is the frequency. Because wavelength (λ) and frequency are connected by the speed of light ©, another useful formula for photon energy is E=hc/λ.

The electromagnetic spectrum spans a wide range of radiation types, distinguished by their energy and wavelength:

  • Radio waves have the lowest energy and longest wavelengths.
  • Microwaves possess slightly higher energy, suitable for radar and cooking.
  • Infrared light (IR) has moderate energy, frequently used in remote controls and night vision.
  • Visible light occupies the mid-range of the spectrum, enabling color perception.
  • Ultraviolet (UV) light, X-rays, and gamma rays have progressively higher energy and can be ionizing—capable of ejecting electrons from molecules, posing health hazards such as cancer.

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Properties of electromagnetic radiation

Electromagnetic radiation travels at a maximum speed of c (approximately 3×108 m/s) in a vacuum. When it passes through a medium, its velocity decreases according to the relationship n=c/v, where n is the index of refraction, v is the radiation’s speed in that medium, and c is the speed of light in a vacuum. As an electromagnetic wave, it consists of oscillating electric and magnetic fields at right angles to each other and to the direction of propagation.

The electromagnetic spectrum ranges from low-frequency, long-wavelength radiation to high-frequency, short-wavelength radiation. At the lower-frequency end are radio waves, which cause electronic oscillations in antennas. Slightly higher in frequency, microwaves induce molecular rotation, while infrared waves lead to molecular vibration.

Visible light can excite electrons within atoms, spanning approximately 400 nm (violet) to 700 nm (red).

Ultraviolet waves carry enough energy to break bonds or eject electrons—often classified as ionizing radiation. X-rays, still more energetic, also ionize matter and can trigger the photoelectric effect.

The highest frequencies belong to gamma rays, which have even greater energies and penetrating power than X-rays.

Visual spectrum, color

The visual spectrum spans a range of wavelengths and frequencies corresponding to different colors. Blue light, with its shortest wavelength and highest frequency, carries the most energy per photon (E=hν), where h is Planck’s constant and ν is frequency), while red light, with its longest wavelength and lowest frequency, has the least energy.
A laser—an acronym for Light Amplification by Stimulated Emission of Radiation—produces light through stimulated emission rather than the spontaneous emission typical of ordinary light. Within the lasing medium, light is repeatedly amplified by reflecting it back and forth, resulting in a coherent and highly focused beam.

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