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5.2 Chemistry
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Chemistry

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Chemistry is the study of matter. This includes the properties, behaviors, and interactions of matter.

Particles

Atoms

Atoms are extremely small particles and the building blocks of all matter. They are made up of a nucleus of protons and neutrons and are surrounded by a “cloud” of electrons.

More than 99% of the mass of an atom is in the nucleus, as electrons are incredibly small compared to protons and neutrons.

Protons have a positive charge. Neutrons have a neutral charge. Electrons have a negative charge.

Protons, neutrons, and electrons in an atom.
Atomic particles
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The opposing charges of the protons and electrons in an atom bind it together.

An atom’s atomic number is the number of protons in an atom.

For example, an oxygen atom has 8 protons, so its atomic number is 8.

An atom’s mass number is the number of protons and neutrons combined.

For example, an oxygen atom with 8 protons and 8 neutrons has a mass number of 16.

Ions

If an atom has the same number of protons and electrons, the atom has a neutral charge. If an atom has an imbalance between protons and electrons, it has a charge and is called an ion.

If an atom has more protons than electrons, it has a positive charge. This is called a positive ion, or cation.

If an atom has more electrons than protons, it has a negative charge. This is called a negative ion, or anion.

Isotopes

Isotopes are atoms of the same element that have the same number of protons but a different number of neutrons.

Isotopes have the same chemical properties as one another, but different mass numbers and physical properties.

Isotopes are often named after their mass number (the number of protons and neutrons combined).

For example, a carbon-12 atom has 6 protons and 6 neutrons.

A carbon-13 atom has 6 protons and 7 neutrons.

And a carbon-14 atom has 6 protons and 8 neutrons.

Unstable Isotopes

If an isotope has too many or too few neutrons, the atom can become unstable and radioactive.

Unstable atoms will break down over time in an attempt to stabilize, releasing harmful particles in a process called radioactive decay.

For example, carbon-12 and carbon-13 are stable, but carbon-14 is radioactive because it has too many neutrons to maintain long-term stability.

States of Matter

Matter exists in four main states: solid, liquid, gas, and plasma.

Solid Matter

Solids maintain a particular shape and volume unless acted on by an outside force. The molecules within a solid are closely packed and cannot freely move. They can only vibrate in place.

Solids can be melted to form liquids.

Liquid Matter

Liquids do not maintain a particular shape; instead, they conform to the shape of the container they are in. Liquids do, however, maintain a set volume. The molecules within a liquid are relatively closely packed but move freely over one another.

Liquids can be heated to make gases or cooled to make solids.

Gas Matter

Gases do not maintain a particular shape or volume and expand to completely fill the container they are in. The molecules within a gas are spread apart and rapidly moving.

Gases can be cooled to form liquids.

Plasma Matter

Plasma is formed when gas becomes superheated, separating electrons from neutrally charged atoms. This creates positive ions and negative, free-floating electrons. The majority of matter in the universe is plasma, and stars are mostly composed of it. Though plasma is less abundant on Earth, it is generated by lightning, neon lights, and sparks.

Four panels. Solid: particles packed in rows, with a definite shape and volume (ice). Liquid: particles close together but not in rows, with a definite volume but no definite shape (water). Gas: particles far apart and moving, with no definite shape or volume (steam). Plasma: positive ions and free electrons, a gas so hot its electrons break free (lightning, stars, neon lights). Arrows between them: melting and freezing, vaporization and condensation, superheating and cooling.
States of Matter
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Temperature

Temperature measures how fast, on average, the particles in a substance are moving. Adding heat speeds the particles up, which is how a solid melts into a liquid and a liquid boils into a gas.

Temperature is measured in degrees Celsius (°C) or degrees Fahrenheit (°F). Science uses Celsius, where water freezes at 0∘C and boils at 100∘C. Everyday temperatures in the United States use Fahrenheit, where water freezes at 32∘F and boils at 212∘F.

To convert Celsius to Fahrenheit, multiply by 59​, then add 32:

F=C×59​+32

To convert Fahrenheit to Celsius, subtract 32, then multiply by 95​:

C=(F−32)×95​

For example, what is 20∘C in Fahrenheit?

F=20×59​+32

F=36+32

F=68∘F

The Periodic Table

An element is a substance made up of atoms that all have the same number of protons. Examples of elements are hydrogen, potassium, and sodium.

For instance, hydrogen is an element with one proton. Sodium is an element with 11 protons.

The Periodic Table is the organization of all known elements in the universe, including some that can only be synthesized. They are arranged by their number of protons and chemical properties.

Chemical Bonding

Because bonded atoms are often more stable than free atoms, they often spontaneously bond together. When atoms or ions combine, they form structures such as molecules or crystals.

Ionic Bonds

An ionic bond typically forms when an atom donates one or more electrons to another atom, resulting in positively charged cations and negatively charged anions. The attraction of their opposite charges helps hold the compound together. This typically happens between a nonmetal and a metal.

Covalent Bonds

Covalent bonds are formed when two atoms share one or more pairs of electrons. This typically happens between two nonmetals.

Electron transfer in ionic bonds and electron sharing in covalent bonds.
Ionic and Covalent Bonds
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Chemical Reactions

A chemical reaction is when one or more substances convert into another substance. The initial substance(s) are called the reactants, and the result is called the product(s). Examples of chemical reactions include burning wood, baking a cake, or digesting food.

As an example, let’s look at the process of photosynthesis. Carbon dioxide and water undergo a chemical reaction to form glucose and oxygen.

6CO2​+6H2​O→C6​H12​O6​+6O2​

Notice how the number of elements is balanced on each side. There are a total of 6 carbon atoms, 18 oxygen atoms, and 12 hydrogen atoms on each side of the equation. This is because matter cannot be created or destroyed; it can only be transformed.

Sidenote
Chemical Reactions vs Physical Transformation

A chemical reaction is different from a physical transformation. For example, water freezing into ice is a physical change because the chemical compound (H2​O) remains the same and does not recombine to form a new compound.

Solutions

A solution is a mixture of substances so blended together that the individual components cannot be observed separately. Air is an example of a solution, as it is mainly a mixture of nitrogen, oxygen, argon, and carbon dioxide. Saltwater or coffee are also examples of solutions.

The majority component in any solution is called the solvent, while the minority component(s) in the solution are called the solute.

The maximum amount of a substance that can be dissolved in a volume of solvent is called solubility.

Water is the most common solvent.

Acids and Bases

Acids and bases are substances that react in a particular way when dissolved. They are classified both by their position on the pH scale and by the ions they form.

pH scale showing acidic, neutral, and basic substances.
pH Scale
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Acids

Acids form hydrogen ions (H+) when dissolved in water. They have a pH less than 7.

Acids typically taste sour and can be corrosive, especially at lower pH levels. Examples of highly acidic substances include stomach acid and lemon juice.

Bases

Bases form hydroxide ions (OH-) when dissolved in water. They have a pH of more than 7.

Bases typically taste bitter and have a slippery feel. Like acids, bases can be corrosive, especially at higher pH levels. Examples of highly basic substances are soap and bleach.

A substance with a pH of 7 is considered neutral. Water typically has a neutral pH.

Atoms & Particles

  • Atoms = building blocks of matter; nucleus (protons + neutrons) surrounded by electron cloud
  • Nucleus holds >99% of mass; protons (+), neutrons (neutral), electrons (−)
  • Atomic number = # protons; mass number = # protons + neutrons (e.g., oxygen: atomic # 8, mass # 16)

Ions & Isotopes

  • Ion: imbalance of protons/electrons creates charge
    • More protons than electrons = cation (+)
    • More electrons than protons = anion (−)
  • Isotopes: same element, same protons, different neutrons → same chemistry, different mass/physical properties
    • Named by mass number (e.g., carbon-12, -13, -14)
  • Unstable isotopes (too many/few neutrons) undergo radioactive decay (e.g., carbon-14 is radioactive; carbon-12/13 stable)

States of Matter

  • Solid: fixed shape & volume, particles vibrate in place
  • Liquid: fixed volume, no fixed shape, particles move freely but stay close
  • Gas: no fixed shape or volume, particles spread out & move rapidly
  • Plasma: superheated gas with separated ions/electrons; most abundant state in universe (stars); on Earth seen in lightning, neon lights
  • Transitions: melting/freezing (solid↔liquid), vaporization/condensation (liquid↔gas), superheating/cooling (gas↔plasma)

Temperature

  • Measures average particle speed; more heat = faster particles = phase changes
  • Celsius: water freezes 0∘C, boils 100∘C; Fahrenheit: freezes 32∘F, boils 212∘F
  • Conversion formulas: F=C×59​+32 and C=(F−32)×95​

Periodic Table & Elements

  • Element = atoms with same # protons (e.g., hydrogen = 1 proton, sodium = 11 protons)
  • Periodic Table organizes all known/synthesized elements by proton count and chemical properties

Chemical Bonding

  • Bonded atoms more stable than free atoms → form molecules/crystals
  • Ionic bond: electron transfer between atoms (metal + nonmetal) → cations/anions attract
  • Covalent bond: electron sharing between atoms (typically nonmetal + nonmetal)

Chemical Reactions

  • Reactants convert to products; matter is conserved (balanced atoms on both sides)
  • Example: photosynthesis — 6CO2​+6H2​O→C6​H12​O6​+6O2​
  • Differs from physical change (e.g., freezing water keeps same compound, no new substance formed)

Solutions

  • Mixture where components are indistinguishable (e.g., air, saltwater)
  • Solvent = majority component; solute = minority component(s)
  • Solubility = max amount of solute dissolvable in a solvent; water is most common solvent

Acids & Bases

  • Classified by pH and ions formed
  • Acids: form H+ ions, pH < 7, taste sour, corrosive (e.g., stomach acid, lemon juice)
  • Bases: form OH− ions, pH > 7, taste bitter, slippery, corrosive (e.g., soap, bleach)
  • pH of 7 = neutral (e.g., water)

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Chemistry

Chemistry is the study of matter. This includes the properties, behaviors, and interactions of matter.

Particles

Atoms

Atoms are extremely small particles and the building blocks of all matter. They are made up of a nucleus of protons and neutrons and are surrounded by a “cloud” of electrons.

More than 99% of the mass of an atom is in the nucleus, as electrons are incredibly small compared to protons and neutrons.

Protons have a positive charge. Neutrons have a neutral charge. Electrons have a negative charge.

The opposing charges of the protons and electrons in an atom bind it together.

An atom’s atomic number is the number of protons in an atom.

For example, an oxygen atom has 8 protons, so its atomic number is 8.

An atom’s mass number is the number of protons and neutrons combined.

For example, an oxygen atom with 8 protons and 8 neutrons has a mass number of 16.

Ions

If an atom has the same number of protons and electrons, the atom has a neutral charge. If an atom has an imbalance between protons and electrons, it has a charge and is called an ion.

If an atom has more protons than electrons, it has a positive charge. This is called a positive ion, or cation.

If an atom has more electrons than protons, it has a negative charge. This is called a negative ion, or anion.

Isotopes

Isotopes are atoms of the same element that have the same number of protons but a different number of neutrons.

Isotopes have the same chemical properties as one another, but different mass numbers and physical properties.

Isotopes are often named after their mass number (the number of protons and neutrons combined).

For example, a carbon-12 atom has 6 protons and 6 neutrons.

A carbon-13 atom has 6 protons and 7 neutrons.

And a carbon-14 atom has 6 protons and 8 neutrons.

Unstable Isotopes

If an isotope has too many or too few neutrons, the atom can become unstable and radioactive.

Unstable atoms will break down over time in an attempt to stabilize, releasing harmful particles in a process called radioactive decay.

For example, carbon-12 and carbon-13 are stable, but carbon-14 is radioactive because it has too many neutrons to maintain long-term stability.

States of Matter

Matter exists in four main states: solid, liquid, gas, and plasma.

Solid Matter

Solids maintain a particular shape and volume unless acted on by an outside force. The molecules within a solid are closely packed and cannot freely move. They can only vibrate in place.

Solids can be melted to form liquids.

Liquid Matter

Liquids do not maintain a particular shape; instead, they conform to the shape of the container they are in. Liquids do, however, maintain a set volume. The molecules within a liquid are relatively closely packed but move freely over one another.

Liquids can be heated to make gases or cooled to make solids.

Gas Matter

Gases do not maintain a particular shape or volume and expand to completely fill the container they are in. The molecules within a gas are spread apart and rapidly moving.

Gases can be cooled to form liquids.

Plasma Matter

Plasma is formed when gas becomes superheated, separating electrons from neutrally charged atoms. This creates positive ions and negative, free-floating electrons. The majority of matter in the universe is plasma, and stars are mostly composed of it. Though plasma is less abundant on Earth, it is generated by lightning, neon lights, and sparks.

Temperature

Temperature measures how fast, on average, the particles in a substance are moving. Adding heat speeds the particles up, which is how a solid melts into a liquid and a liquid boils into a gas.

Temperature is measured in degrees Celsius (°C) or degrees Fahrenheit (°F). Science uses Celsius, where water freezes at 0∘C and boils at 100∘C. Everyday temperatures in the United States use Fahrenheit, where water freezes at 32∘F and boils at 212∘F.

To convert Celsius to Fahrenheit, multiply by 59​, then add 32:

F=C×59​+32

To convert Fahrenheit to Celsius, subtract 32, then multiply by 95​:

C=(F−32)×95​

For example, what is 20∘C in Fahrenheit?

F=20×59​+32

F=36+32

F=68∘F

The Periodic Table

An element is a substance made up of atoms that all have the same number of protons. Examples of elements are hydrogen, potassium, and sodium.

For instance, hydrogen is an element with one proton. Sodium is an element with 11 protons.

The Periodic Table is the organization of all known elements in the universe, including some that can only be synthesized. They are arranged by their number of protons and chemical properties.

Chemical Bonding

Because bonded atoms are often more stable than free atoms, they often spontaneously bond together. When atoms or ions combine, they form structures such as molecules or crystals.

Ionic Bonds

An ionic bond typically forms when an atom donates one or more electrons to another atom, resulting in positively charged cations and negatively charged anions. The attraction of their opposite charges helps hold the compound together. This typically happens between a nonmetal and a metal.

Covalent Bonds

Covalent bonds are formed when two atoms share one or more pairs of electrons. This typically happens between two nonmetals.

Chemical Reactions

A chemical reaction is when one or more substances convert into another substance. The initial substance(s) are called the reactants, and the result is called the product(s). Examples of chemical reactions include burning wood, baking a cake, or digesting food.

As an example, let’s look at the process of photosynthesis. Carbon dioxide and water undergo a chemical reaction to form glucose and oxygen.

6CO2​+6H2​O→C6​H12​O6​+6O2​

Notice how the number of elements is balanced on each side. There are a total of 6 carbon atoms, 18 oxygen atoms, and 12 hydrogen atoms on each side of the equation. This is because matter cannot be created or destroyed; it can only be transformed.

Sidenote
Chemical Reactions vs Physical Transformation

A chemical reaction is different from a physical transformation. For example, water freezing into ice is a physical change because the chemical compound (H2​O) remains the same and does not recombine to form a new compound.

Solutions

A solution is a mixture of substances so blended together that the individual components cannot be observed separately. Air is an example of a solution, as it is mainly a mixture of nitrogen, oxygen, argon, and carbon dioxide. Saltwater or coffee are also examples of solutions.

The majority component in any solution is called the solvent, while the minority component(s) in the solution are called the solute.

The maximum amount of a substance that can be dissolved in a volume of solvent is called solubility.

Water is the most common solvent.

Acids and Bases

Acids and bases are substances that react in a particular way when dissolved. They are classified both by their position on the pH scale and by the ions they form.

Acids

Acids form hydrogen ions (H+) when dissolved in water. They have a pH less than 7.

Acids typically taste sour and can be corrosive, especially at lower pH levels. Examples of highly acidic substances include stomach acid and lemon juice.

Bases

Bases form hydroxide ions (OH-) when dissolved in water. They have a pH of more than 7.

Bases typically taste bitter and have a slippery feel. Like acids, bases can be corrosive, especially at higher pH levels. Examples of highly basic substances are soap and bleach.

A substance with a pH of 7 is considered neutral. Water typically has a neutral pH.

Key points

Atoms & Particles

  • Atoms = building blocks of matter; nucleus (protons + neutrons) surrounded by electron cloud
  • Nucleus holds >99% of mass; protons (+), neutrons (neutral), electrons (−)
  • Atomic number = # protons; mass number = # protons + neutrons (e.g., oxygen: atomic # 8, mass # 16)

Ions & Isotopes

  • Ion: imbalance of protons/electrons creates charge
    • More protons than electrons = cation (+)
    • More electrons than protons = anion (−)
  • Isotopes: same element, same protons, different neutrons → same chemistry, different mass/physical properties
    • Named by mass number (e.g., carbon-12, -13, -14)
  • Unstable isotopes (too many/few neutrons) undergo radioactive decay (e.g., carbon-14 is radioactive; carbon-12/13 stable)

States of Matter

  • Solid: fixed shape & volume, particles vibrate in place
  • Liquid: fixed volume, no fixed shape, particles move freely but stay close
  • Gas: no fixed shape or volume, particles spread out & move rapidly
  • Plasma: superheated gas with separated ions/electrons; most abundant state in universe (stars); on Earth seen in lightning, neon lights
  • Transitions: melting/freezing (solid↔liquid), vaporization/condensation (liquid↔gas), superheating/cooling (gas↔plasma)

Temperature

  • Measures average particle speed; more heat = faster particles = phase changes
  • Celsius: water freezes 0∘C, boils 100∘C; Fahrenheit: freezes 32∘F, boils 212∘F
  • Conversion formulas: F=C×59​+32 and C=(F−32)×95​

Periodic Table & Elements

  • Element = atoms with same # protons (e.g., hydrogen = 1 proton, sodium = 11 protons)
  • Periodic Table organizes all known/synthesized elements by proton count and chemical properties

Chemical Bonding

  • Bonded atoms more stable than free atoms → form molecules/crystals
  • Ionic bond: electron transfer between atoms (metal + nonmetal) → cations/anions attract
  • Covalent bond: electron sharing between atoms (typically nonmetal + nonmetal)

Chemical Reactions

  • Reactants convert to products; matter is conserved (balanced atoms on both sides)
  • Example: photosynthesis — 6CO2​+6H2​O→C6​H12​O6​+6O2​
  • Differs from physical change (e.g., freezing water keeps same compound, no new substance formed)

Solutions

  • Mixture where components are indistinguishable (e.g., air, saltwater)
  • Solvent = majority component; solute = minority component(s)
  • Solubility = max amount of solute dissolvable in a solvent; water is most common solvent

Acids & Bases

  • Classified by pH and ions formed
  • Acids: form H+ ions, pH < 7, taste sour, corrosive (e.g., stomach acid, lemon juice)
  • Bases: form OH− ions, pH > 7, taste bitter, slippery, corrosive (e.g., soap, bleach)
  • pH of 7 = neutral (e.g., water)

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